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Basic Information

Item Specification
Product Full Name Sodium Trimetaphosphate
Abbreviation STMP
CAS No. 7785-84-4
E Number E 451(i)
Molecular Formula (NaPO₃)₃
Molecular Weight 305.89
Appearance White crystalline powder
Solubility Freely soluble in water, insoluble in ethanol
pH Value (1% Solution) 5.0 – 7.0
Grade Food Grade, Industrial Grade
Executive Standard FCC, E451(i), GB 1886.326
Certifications ISO9001, HALAL, KOSHER
Core Characteristic Unique cyclic polyphosphate structure with excellent cross-linking performance
HS Code  2835299000

 

Product Overview 

Sodium Trimetaphosphate (STMP) is a cyclic polyphosphate with stable chemical structure and high water solubility. Its most distinctive property is acting as an efficient cross-linking agent in food systems, widely utilized for starch modification to improve structural stability, thermal resistance, and anti-retrogradation performance of starch materials.

In starch-based food processing, STMP promotes molecular cross-linking, forming a compact and uniform network structure that enhances elasticity, toughness, and water retention of finished products such as rice noodles and vermicelli.

In addition to its core cross-linking function, STMP serves as a sequestering agent to bind metal ions, effectively inhibiting oxidation, discoloration, and sedimentation in food formulations, maintaining stable sensory quality and extending shelf performance. It is also applied in certain industrial scenarios for metal ion regulation and water treatment.

 

Character

Sodium Trimetaphosphate appears as a white, odorless crystalline powder with stable physical and chemical properties under normal storage conditions.

Compared with linear phosphates, its unique cyclic molecular structure provides superior cross-linking reactivity with starch and protein molecules. It exhibits excellent compatibility with various food raw materials, with low impurity and heavy metal content that fully complies with international food additive safety standards.

 

Main Functions

 

1. Cross-linking Agent 

As the most representative function of STMP, it cross-links starch molecular chains during processing. This reaction rebuilds a stable three-dimensional network structure, significantly improving thermal stability, freeze-thaw resistance, and anti-aging performance of modified starch. It effectively enhances the toughness, elasticity, and structural firmness of starch-based foods.

2. Sequestering Agent

STMP chelates calcium, magnesium, iron and other metal ions in food systems. It reduces catalytic oxidation reactions, prevents product discoloration, turbidity and precipitation, and maintains uniform texture and stable appearance of food products.

3. Texture Stabilizer

Optimizes the water retention capacity and structural uniformity of starch and gel foods, reducing breakage rate during cooking and processing, and improving overall texture consistency.

 

Applications

 

1. Food Industry 

Modified Starch Production: STMP is a key cross-linking phosphate reagent for producing cross-linked modified starch. Modified starch treated with STMP possesses better heat resistance, shear resistance and storage stability, widely used in food thickening, filling and stabilizing systems.

Starch-Based Noodle Products: Applied in rice noodles, vermicelli, and pasta products to enhance ductility and toughness, reduce breakage, improve water locking performance, and prevent soup turbidity during cooking.

Gel & Canned Food: Stabilizes gel structure, improves texture uniformity, and inhibits metal-induced deterioration in canned foods and jelly systems.

2. Industrial Application 

Used in water treatment, ceramic manufacturing and detergent industries for metal ion sequestration and system stabilization.

 

Packaging & Storage

Packaging: 25kg PE lined kraft paper bag, 1000kg bulk jumbo bag, customizable packaging available.

Storage: Store in cool, dry and ventilated warehouse, keep sealed to avoid moisture absorption and contamination.

Shelf Life: 24 months under proper storage conditions.

CERTIFICATE OF ANALYSIS

Sodium Trimetaphosphate-Food grade

Cas.No.

7785-84-4

ITEMS

SPECIFICATIONS

RESULT

Appearance

White crystal powder

Assay(as(NaPO3)3      %≥

98.5

99.2

P2O5 %≥

69

69.1

PH (10g/L    water solution)

6.0-9.0

7.4

Heavy Metal(As Pb)%≤

0.001

<0.001

Arsenic    %≤

0.0003

0.0002

Fluoride    %≤

0.001

0.0006

Water Insoluble %≤

0.05

<0.05

Zinc %≤

0.001

NIL

Fe2O3 %≤

0.002

<0.001

Lead %≤

0.0002

0.0001

Particle size(Passing through 80

mesh) %≥

90

96.4

Product Name: Sodium trimetaphosphate Other Name: Metaphosphoric acid (H3P3O9),sodium salt (1:3);Metaphosphoric acid (H3P3O9),trisodium salt;Sodium metaphosphate (Na3(P3O9));Sodium metaphosphate;Sodium trimetaphosphate;Sodium metaphosphate ((NaPO3)3);Trisodium metaphosphate;Trisodium trimetaphosphate (Na3P3O9);Trisodium trimetaphosphate;Cyclic sodium trimetaphosphate;Trimetaphosphoric acid (H3P3O9),trisodium salt;Sodium phosphate ((NaPO3)3);Trisodium cyclotriphosphate;Detoxol;Trisodium tricyclophosphate;STMP;Sodium phosphate (Na3P3O9);Sodium cyclotriphosphate (Na3P3O9);Polyrinsan 5B
CAS No.: 7785-84-4 Molecular Formula: H3O9P3.3Na
InChIKeys: InChIKey=QXLZJPAXEGLSGU-UHFFFAOYSA-N Molecular Weight: 305.88500
Exact Mass: 305.84500 EC Number: 232-088-3
UNII: 3IH6169RL0 DSSTox ID: DTXSID7052789
HScode: 2835399000 Categories: Water Retention Agent

PSA: 177.51000 XLogP3: 1.66560
Appearance: White crystalline powder Density: 3″>2.49 g/cm3
Melting Point: 588ºC Refractive Index: COLORLESS; INDEX OF REFRACTION: 1.433, 1.442, 1.446 /HEXAHYDRATE/
Water Solubility: Soluble in water. Insoluble in alcohol. Storage Conditions: Keep in a cool, dry location in a closed container.
Experimental Properties: Loses water on storage at 20 °C, becomes definitely anhydrous at 100 °C. /Hexahydrate/|Efflorescent, triclinic-rhombohedral prisms. Melting point 53 °C. Specific gravity 1.786. One gram dissolves in 4.5 ml water. Insol in alc. /Hexahydrate/

Classification of the substance or mixture

Not classified.

GHS label elements, including precautionary statements

Pictogram(s) No symbol.
Signal word

No signal word

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none

Other hazards which do not result in classification

no data available

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.