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Basic Information

 

Item Specification
Product Full Name Sodium Hexametaphosphate
Abbreviation SHMP
CAS No. 10124-56-8
E Number E 452(i)
Molecular Formula (NaPO₃)₆
Molecular Weight 611.76
Appearance White powder or glassy granules
Solubility Freely soluble in water, insoluble in organic solvents
pH Value (1% aqueous solution, 25℃) 6.0 ~ 6.8
Available Grade Food Grade, Industrial Grade
Executive Standard FCC, E 452(i), GB 1886.333
Certifications ISO9001, HALAL, KOSHER, Reach
Core Characteristic Long-chain polyphosphate structure with powerful metal ion chelation capacity

 

Product Overview 

Sodium Hexametaphosphate (SHMP) is a long-chain polyphosphate salt with high water solubility and strong metal ion binding capacity. It is widely used as a sequestering agent and water retention agent in food processing.

SHMP effectively chelates calcium, magnesium and other metal ions in food systems, preventing undesirable crystal formation, discoloration and sediment precipitation. In canned seafood, it suppresses struvite crystal development that causes gritty texture. In meat and seafood processing, it assists in water retention, reducing cooking loss and maintaining tender, juicy texture.

SHMP also functions as a dispersing agent, helping to maintain uniform particle distribution and system stability. It is applied in dairy products, processed cheese, beverages, fruit and vegetable processing, as well as selected industrial fields such as water treatment and detergent formulations.

 

Character

Sodium Hexametaphosphate appears as a white powder or glassy granular solid. It dissolves readily in water to form nearly neutral aqueous solutions, and remains stable under proper storage conditions.

Its long-chain polyphosphate structure provides exceptionally strong sequestering capacity compared with shorter-chain phosphates. SHMP has low heavy metal and impurity content, meeting international food additive safety specifications. It is compatible with a wide range of food raw materials and processing conditions.

 

Main Functions

1.Strong Sequestering & Water Retention Agent:  Powerfully chelate calcium, magnesium and other metal ions to prevent crystal precipitation, discoloration and oxidation in food systems. Deliver water retention performance for meat, poultry and seafood products to reduce cooking loss and maintain tender texture.

2.Dispersing & Anti-Crystallization Agent: Disperse solid particles and suppress undesirable crystal formation in canned seafood, beverages and other food formulations, maintaining uniform texture and preventing gritty or sandy mouthfeel.

3.Emulsifying & Stabilizing Agent: Stabilize food matrix and improve texture consistency in dairy products and processed cheese.

 

Applications

1.Food Formulations 

Canned Seafood & Frozen Seafood: Inhibit struvite crystal formation, prevent discoloration and maintain fresh color and texture of canned fish, shellfish and frozen seafood products.

Processed Meat & Poultry: Assist in water retention, reduce cooking loss and improve tenderness and yield of ham, sausage and processed meat products.

Beverages & Fruit/Vegetable Processing: Chelate metal ions to prevent turbidity, precipitation and enzymatic browning, maintain clear and stable product appearance.

Dairy & Processed Cheese: Stabilize system matrix and improve texture uniformity.

 

2. Industrial Applications

Applied in water treatment, detergent formulations and ceramic processing for metal ion control and dispersion performance.

 

3.Animal Feed

Occasionally used in special feed formulations, not as mainstream feed phosphate source.

 

Packaging & Storage

Packaging: 25kg PE lined kraft paper bag, 1000kg jumbo bag. Custom packaging available.

Storage: Store in cool, dry, ventilated warehouse, keep bags sealed to avoid moisture absorption and caking.

Shelf Life: 24 months under proper storage conditions.

CERTIFICATE OF ANALYSIS (SAMPLE)

Sodium Hexametaphosphate (Tech Grade)

 

Grade

Tech Grade

E number(s) N/A

Formula

(NaPO3)6

Molecular weight

611.77

EINECS

233-343-1

CAS number

10124-56-8

Chemical properties

Unit

Typical analysis

Specifications

Total P2O5

%

68.2

68.0MIN

Inactive Phosphate

%

6.1

7.5MAX

Water Insoluble

%

0.03

0.05MAX

Iron (Fe)

%

0.03

0.05MAX

Phof 1% Solution

/

6.3

5.8-7.3

Solubility

%

Pass

Pass

Appearance

/

Pass

White Flake, Granular, Powder

 

CERTIFICATE OF ANALYSIS

 

Sodium Hexametaphosphate Food Grade

 

Grade

Food grade

E number(s) E 452(i)

Formula

Na6O18P6

Molecular weight

611.77

EINECS

233-343-1

CAS number

10124-56-8

Chemical properties

Unit

Typical analysis

Specifications

Total P2O5

%

68.3

68.0-69.0

Inactive phosphate

%

6.5

7.5 MAX

Water insoluble

%

0.005

0.05 MAX

Ph (1% solution)

 

6.8

5.8-7.0

Loss on ignition

%

0.7

1 MAX

Fluoride

ppm

0.02

10 MAX

Pb

ppm

0.01

1 MAX

As

ppm

0.03

1 MAX

Cd

ppm

0.05

1 MAX

Hg

ppm

0.01

1 MAX

Fe

ppm

25

100 MAX

Heavy metal (as Pb)

ppm

<10

10 MAX

Solubility

 

Pass

Pass

Test for sodium

 

Pass

Pass

Test for phosphate

 

Pass

Pass

Appearance

 

Pass

White Flake, Granular or Powder

 

 

Product Name: Sodium phosphate (Na6P6O18) Other Name: Metaphosphoric acid (H6P6O18),sodium salt (1:6);Metaphosphoric acid (H6P6O18),hexasodium salt;Sodium hexametaphosphate (Na6P6O18);Sodium phosphate (NaPO3)6;Sodium phosphate (Na6P6O18);Sodium phosphate (Na6(PO3)6);Sodium metaphosphate (Na6(PO3)6);Sodium metaphosphate (Na6P6O18);Sodium hexametaphosphate ((NaPO3)6);Hexasodium hexametaphosphate;8012-14-4;16210-45-0;20517-55-9;193678-44-3;1357387-91-7
CAS No.: 10124-56-8 Molecular Formula: H6O18P6.6Na
InChIKeys: InChIKey=RWTSDYJZARIKCW-UHFFFAOYSA-N Molecular Weight: 611.77000
Exact Mass: 611.69000 HScode: 2835391900
Categories: Preservative

PSA: 387.19000 XLogP3: 3.28080
Appearance: White granular solid Density: 2.181
Melting Point: 616℃ Refractive Index: 1.482
Storage Conditions: Store in a cool, dry place. Store in a tightly closed container.

Classification of the substance or mixture

Not classified.

GHS label elements, including precautionary statements

Pictogram(s) No symbol.
Signal word

No signal word

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none

Other hazards which do not result in classification

no data available

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.