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Basic Product Information:

 

Parameter Details
English Name Magnesium Citrate
Synonyms Trimagnesium Dicitrate
E Number E332 
Appearance White crystalline powder
Solubility Solubility varies with hydration forms
Odor Odorless
Available Forms Anhydrous, Nonahydrate, Dodecahydrate

 

Magnesium Citrate Hydrate Grades Comparison Table

 

Hydrate Type Common Name CAS Number Molecular Formula Core Characteristics Main Applications
Anhydrous Magnesium Citrate Anhydrous 3344-18-1 C₆H₄Mg₃O₇ Highest magnesium content, low moisture, good thermal stability Dietary supplements, pharmaceutical formulations
Nonahydrate Magnesium Citrate Nonahydrate 153531-96-5 C₆H₄Mg₃O₇·9H₂O Excellent water solubility, high bioavailability, moderate magnesium content Food fortification, magnesium supplement raw material, functional beverages
Dodecahydrate Magnesium Citrate Dodecahydrate 1198-97-6 C₆H₄Mg₃O₇·12H₂O High crystal water, mild taste, stable crystal structure Food acidity regulator, nutritional powder, solid supplement formulations

 

Product Overview

Magnesium Citrate (E345) is a series of food-grade organic chelated magnesium salts, mainly available in Magnesium Citrate Anhydrous, Magnesium Citrate Nonahydrate, and Magnesium Citrate Dodecahydrate.  As a premium bioavailable magnesium fortifier and professional acidity regulator, it outperforms inorganic magnesium sources in absorption efficiency and gastrointestinal tolerance.

This product series stabilizes system pH, modifies unpleasant mineral metallic taste, optimizes powder fluidity, and prevents caking. It is extensively applied in dietary supplements, chewable tablets, multivitamin mineral premixes, and solid beverage formulations.

Character

1.All grades are odorless crystalline powder with clean, mild taste, no harsh bitterness, friendly for flavored food formulations.

2.Organic chelated magnesium structure delivers far higher bioavailability than magnesium oxide and magnesium hydroxide, ensuring efficient magnesium nutrient absorption.

3.Mild acidic buffering property enables precise pH adjustment without drastic system pH fluctuation, protecting formula stability.

4.Low gastrointestinal irritation at standard dosage, suitable for long-term nutritional supplement formulations.

5.Good thermal stability under conventional food processing and storage conditions, no easy decomposition or ingredient reaction.

6.Excellent powder dispersion performance, compatible with various vitamin and mineral premix systems.

7.Three water-content grades cover diverse formula demands: high flowability, balanced magnesium content, and mild taste customization.

8.Fully compliant with global food safety standards and religious certifications, suitable for worldwide food and supplement export.

 

Main Functions

1.High-Bioavailability Magnesium Fortification Function Serves as an efficient organic magnesium fortifier, providing easily absorbable magnesium nutrition for human body. It compensates daily magnesium deficiency, supports body basic metabolism, and is the core nutritional additive for dietary supplements and functional solid foods.

2.Professional Acidity Regulation & pH Buffering Function Acts as a stable acidity regulator in food systems. It moderately neutralizes excess acidity, balances overall formula sourness, maintains long-term stable pH value of tablets, powder premixes and solid beverages, and avoids quality deterioration caused by pH drift.

3.Professional Taste Modifying & Flavor Stabilizing Function Effectively covers and reduces the metallic bitter and astringent taste brought by inorganic minerals in compound premixes. It optimizes the mouthfeel of chewable tablets and solid drinks, locks fresh flavor during storage, and improves finished product palatability.

4.Anti-Caking & Powder Flow Optimizing Function Improves the bulk fluidity of mixed mineral and vitamin powders, reduces fine powder agglomeration and moisture caking during production, filling and storage. It ensures uniform ingredient mixing and consistent finished product quality.

 

Applications

1.Food & Dietary Supplement Industry

This Magnesium Citrate series is the preferred magnesium fortification and acidity regulation material for global nutraceutical manufacturers.

Magnesium Citrate Nonahydrate : – Maximum market dosage Widely used in regular dietary supplement tablets, hard capsules, daily multivitamin mineral premixes, and ordinary solid beverages. Its outstanding flowability and formula compatibility make it the most cost-effective and universal grade for mass production.

Magnesium Citrate Anhydrous:  Applied in high-end nutritional powders, high-dose magnesium supplement tablets and capsules. Features high magnesium content and low moisture absorption, ideal for formulas requiring strict moisture control.

Magnesium Citrate Dodecahydrate: Mainly used in high-demand mild-taste chewable tablets, children’s nutritional powders and low-irritation functional solid drinks, focusing on taste optimization and mild formula performance.

2.Confectionery & Functional Solid Food 

Suitable for pressed candies, functional snack powders and fortified cereal products. It achieves dual effects of mineral nutrition enhancement and taste optimization without affecting product original flavor and texture.

3. Pharmaceutical Industry 

Pharma-grade Magnesium Citrate (mainly Nonahydrate and Anhydrous) is used in oral nutritional preparations and mild conditioning formulations, with limited industrial consumption, not the core business scope.

 

Packaging and Storage

Packaging: 25kg multi-ply paper bags with inner PE liner; jumbo bags (500kg/1000kg) for bulk shipment; fiber drum packaging available for pharmaceutical-grade products.

Storage Requirements: Store in cool, dry, ventilated warehouse. Keep away from moisture, strong acid substances, direct sunlight and high heat environment.

 

 

Specification

USP36

EP8.0

Content (Mg),w/%

14.5-16.4

15.0-16.5

Calcium (Ca),w/%       ≤

1.0

0.2

Iron (Fe),w/%           ≤

0.02

0.01

Arsenic (As),w/%        ≤

0.0003

————

Chloride,w/%           ≤

0.05

————

Heavy metal,w/%        ≤

0.005

0.001

Sulphate,w/%           ≤

0.2

0.2

pH (5% solution)

5.0-9.0

6.0-8.5

Loss on drying,w/%      ≤

29.0

24.0-28.0

Oxide,w/%           ≤

————

0.028

Product Name: Magnesium citrate anhydrous CAS No.: 153531-96-5
Molecular Formula: C12H28Mg3O23 InChIKeys: IYQJAGXFXWIEJE-UHFFFAOYSA-H
Molecular Weight: 613.25192 Exact Mass: 612.057251
EC Number: 222-093-9 Categories: Nutrition Supplements

PSA: 281.33000 XLogP3: -3.53830
Water Solubility: Sparingly soluble in water, practically insoluble in ethanol (96 per cent). It dissolves in dilute hydrochloric acid.

Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity – single exposure, Category 3

GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

Precautionary statement(s)
Prevention

P264 Wash … thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

Response

P302+P352 IF ON SKIN: Wash with plenty of water/…

P321 Specific treatment (see … on this label).

P332+P317 If skin irritation occurs: Get medical help.

P362+P364 Take off contaminated clothing and wash it before reuse.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P319 Get medical help if you feel unwell.

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.