top of page

Ammonium Bicarbonate

1. Core Product Basic Information

Product Name: Ammonium Bicarbonate

CAS Number: 1066-33-7

EINECS Number: 213-911-5

E Number: E503

Molecular Formula: NH₄HCO₃

Grade: Food Grade / Industrial Grade

Appearance: White crystalline powder, odorless or with slight ammonia odor

Solubility: Soluble in water; insoluble in ethanol, acetone and ammonia

pH Value: 7.8–8.2 (0.1 mol/L aqueous solution)


2. Product Introduction

Ammonium Bicarbonate (E503, CAS 1066-33-7) is an inorganic ammonium salt produced through controlled carbonization, crystallization and purification processes. As a food additive, it is widely used as a leavening agent and pH regulator in food processing.

Food Grade Ammonium Bicarbonate decomposes easily under heating conditions and releases carbon dioxide and ammonia gas. This property makes it especially suitable for flat baked goods, biscuits, crackers and dry bakery products, where it helps achieve desired volume, crispness and uniform texture. It is also used as a processing aid in certain food and beverage systems.


3. Main Functions

Food Grade Core Functions (Detailed)

Leavening Agent Ammonium Bicarbonate decomposes when heated and releases gas. This reaction expands dough and batter structure, producing light, crisp and uniform texture in biscuits, crackers, cookies and similar bakery products.

pH Regulator & Buffer It helps adjust and maintain alkalinity in food systems. By controlling pH during processing, it supports stable reaction conditions and influences final product texture and flavor.

Processing Aid It acts as a processing aid in bakery and beverage production. It may assist in dough development, gas formation and structure improvement in specific food formulations.

Ammonia Source for Fermentation In some fermentation systems, it can serve as a nitrogen source and help create a favorable environment for microbial growth.

 

Industrial Grade Functions 

Used as a nitrogen source in fertilizers

Applied in pharmaceutical and chemical intermediate production

Used in certain industrial buffering and crystallization processes


4. Applications

Food Grade Applications

Biscuits, cookies and crackers

Flat baked goods and dry bakery products

Bread and pastry production

Beverages and food processing aids

Fermentation and nutrient preparation systems

Industrial Grade Applications (Brief)

Fertilizer industry

Pharmaceutical intermediates

Chemical synthesis


5. Package and Storage

Packaging

Standard packaging: 25 kg net per bag

Inner liner: PE liner for moisture protection

Bulk packaging: 500 kg / 1000 kg jumbo bags available

Custom packaging available upon request

Storage

Store in a cool, dry and well-ventilated warehouse

Keep the package tightly sealed

Protect from moisture, rain and direct sunlight

Avoid high temperature and incompatible acids

Recommended shelf life: 2 years under proper storage conditions

Use opened packages as soon as possible and reseal tightly

Product Name: Ammonium bicarbonate Other Name: Carbonic acid,ammonium salt (1:1);Carbonic acid,monoammonium salt;Ammonium bicarbonate;Ammonium hydrogen carbonate;Ammonium bicarbonate ((NH4)HCO3);Monoammonium carbonate;Acid ammonium carbonate;AmBic;114459-02-8;758-14-5;861794-52-7
CAS No.: 1066-33-7 Molecular Formula: CH2O3.H3N
InChIKeys: InChIKey=ATRRKUHOCOJYRX-UHFFFAOYSA-N Molecular Weight: 79.05530
Exact Mass: 79.02690 EC Number: 233-786-0
UNII: 45JP4345C9 ICSC Number: 1333
UN Number: 3077 DSSTox ID: DTXSID5035618
Color/Form: Colorless or white crystals|Shiny, hard, colorless or white prisms or crystalline mass HScode: 2836994000
Categories: Emulsifier

PSA: 60.77000 XLogP3: 0.5463
Appearance: White crystalline powder Density: 3″>1.586 g/cm3
Melting Point: 107 °C (decomp) Boiling Point: 169.8ºC
Refractive Index: INDEX OF REFRACTION: 1.423, 1.536, 1.555 Water Solubility: H2O: 220 g/L (20 ºC)
Storage Conditions: Storage Room low temperature ventilation drying Vapor Pressure: 2.58E-05mmHg at 25°C
Vapor Density: 2.7 (vs air) Odor: Faint odor of ammonia
PH: About 8,0 (5 % solution) Dissociation Constants: Dissociation constant (Kd): 1.45
Experimental Properties: Comparatively stable at room temperature. Volatile with decomposition at about 60 °C. The white fumes given off consist of NH3 21.5%, CO2 55.7%, H2O vapor 22.8%. Rate of decomposition increases as temperature rises. Negative heat of solution.|May attack copper, nickel and zinc.|Heat of solution: 26.4 kJ at 288.2 K Air and Water Reactions: Soluble in water.
Reactive Group: Salts, Basic Reactivity Alerts: Decomposes at Elevated Temperatures (
Reactivity Profile: AMMONIUM BICARBONATE decomposes when heated above 36°C, releasing ammonia and carbon dioxide gases; it can also be decomposed into ammonia and carbon dioxide by strong acids and strong bases [Handling Chemicals Safely 1980 p. 141].

Classification of the substance or mixture

Acute toxicity – Category 4, Oral

GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H302 Harmful if swallowed

Precautionary statement(s)
Prevention

P264 Wash … thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

Response

P301+P317 IF SWALLOWED: Get medical help.

P330 Rinse mouth.

Storage

none

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from strong oxidants, strong bases and acids. Cool.Store below 33 deg C